Fred L. Cook

801 Ferst Drive
Georgia Institute of Technology
School of Textile & Fiber Engineering
Atlanta, GA 30332-0295
Phone: 404-894-2536
FAX: 404-894-8780
e-mail: fred.cook@tfe.gatech.edu

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Last Updated: May 11, 1998

New Aspects in the Stabilization of Acrylic Fibers for Carbon Fibers"

Abstract
The kinetic and morphological influences of nitrogen, air and ammonia in the environment for stabilization of PAN-based precursors for carbon fibers have been investigated. A careful thermal analysis conducted earlier by L. H. Peebles et al. identified ammonia to be a possible accelerator of the reactions. The present study shows that ammonia does increase the rate of stabilization, but the presence of oxygen with ammonia is essential to reach rapidly the stabilized state suitable for carbonization. The preliminary results from X-ray scattering and elemental analyses also suggest that the influence of ammonia is not just to accelerate the stabilization reactions, but also to cause the reaction paths to be different.